Duplex stainless steels are called “duplex” because they have a two-phase microstructure consisting of grains of ferritic and austenitic stainless steel. When duplex stainless steel is melted it solidifies from the liquid phase to a completely ferritic structure. As the material cools to room temperature, about half of the ferritic grains transform to austenitic grains (“islands”). The result is a microstructure of roughly 50% austenite and 50% ferrite. Duplex stainless steels are about twice as strong as regular austenitic or ferritic stainless steels.
Shah International supplies the below Duplex Alloy Grades : Duplex 2205/F51, Ferralium 255, Super Duplex 2507/F53, Super Duplex F55
Duplex 2205 is a nitrogen enhanced duplex stainless steel that was developed to combat common corrosion problems encountered with the 300 series stainless steels. “Duplex” describes a family of stainless steels that are neither fully austenitic, like 304 stainless, nor purely ferritic, like 430 stainless. The structure of 2205 duplex stainless steel consists of austenite pools surrounded by a continuous ferrite phase. In the annealed condition, 2205 contains approximately 40-50% ferrite. Often referred to as the work horse grade, 2205 is the most widely used grade in the duplex family of stainless steels. The advantage of a duplex structure is that it combines the favorable qualities of a ferritic alloy (stress corrosion cracking resistance and high strength) with those of an austenitic alloy (ease of fabrication and corrosion resistance). Usage of 2205 Duplex stainless steel should be limited to temperatures below 600° F. Extended elevated temperature exposure can embrittle 2205 stainless.
Duplex 2205 Chemical Composition, %:
Cr |
Ni |
Mo |
C |
N |
Mn |
Si |
P |
S |
Fe |
22.0-23.0 |
4.50-6.50 |
3.00-3.50 |
0.03 max |
0.14-0.20 |
2.00 max |
1.00 max |
0.03 max |
0.02 max |
Balance |
Duplex 2205 ASTM Specification:
At Room Temperature, Investment Castings As Cast
Pipe Smls |
Pipe Welded |
Tube Smls |
Tube Welded |
Sheet / Plate |
Bar |
Fitting |
A790 |
A790 |
A789 |
A789 |
A240 |
A276 |
A182 |
Mechanical Properties of Duplex 2205:
At Room Temperature, Investment Castings As Cast
Ultimate Tensile Strength |
95 ksi minimum |
Yield |
(0.2 % offset) |
Ferralium 255 is a super duplex stainless steel supplied in the hot worked and annealed condition. It achieves higher strengths than most stainless steels and alternative corrosion resistant alloys, offering the potential to reduce section size and therefore weight and cost. As a 25% Cr alloy, with significant additions of copper, Ferralium® 255 offers excellent corrosion resistance in a wide variety of corrosive chemicals including sulphuric, nitric and phosphoric acid. In seawater and other chloride containing environments it also provides outstanding resistance to pitting and crevice corrosion, with Critical Pitting Temperature exceeding 50°C. Excellent ductility and impact strength at both ambient and sub-zero temperatures combine with a high resistance to abrasion, erosion and cavitation erosion.
Ferralium 255 Chemical Composition, %:
Cr |
Ni |
Mo |
Cu |
C |
Mn |
N |
Si |
P |
S |
Fe |
24.5-26.5 |
5.5-6.5 |
3.1-3.8 |
1.5-2.0 |
0.025 max |
0.8-1.2 |
0.20-0.25 |
0.70 max |
0.025 max |
0.005 max |
Balance |
Ferralium 255 ASTM Specification:
Pipe Smls |
Pipe Welded |
Tube Smls |
Tube Welded |
Sheet / Plate |
Bar |
A790 |
A790 |
A789 |
A789 |
A240 |
A479 |
Mechanical Properties of Ferralium 255:
Ultimate Tensile Strength |
110 ksi or 760 Mpa minimum |
Yield |
(0.2 % offset) |
Elongation |
15 % |
Duplex 2507 is a super duplex stainless steel designed for applications which demand exceptional strength and corrosion resistance. Alloy 2507 has 25% chromium, 4% molybdenum, and 7% nickel. This high molybdenum, chromium and nitrogen content results in excellent resistance to chloride pitting and crevice corrosion attack and the duplex structure provides 2507 with exceptional resistance to chloride stress corrosion cracking. Usage of Duplex 2507 should be limited to applications below 600° F (316° C). Extended elevated temperature exposure can reduce both the toughness and corrosion resistance of alloy 2507. Duplex 2507 possesses excellent mechanical properties. Often a light gauge of 2507 material can be used to achieve the same design strength of a thicker nickel alloy. The resulting savings in weight can dramatically reduce the overall cost of fabrication.
Super Duplex 2507 Chemical Composition, %:
Cr |
Ni |
Mo |
C |
N |
Mn |
Si |
Cu |
P |
S |
Fe |
24.0-26.0 |
6.0-8.0 |
3.0-5.0 |
0.03 max |
0.24-0.32 |
1.20 max |
0.80 max |
0.50 max |
0.035 max |
0.02 max |
Balance |
Super Duplex 2507 ASTM Specification:
Pipe Smls |
Pipe Welded |
Tube Smls |
Tube Welded |
Sheet / Plate |
Bar |
Fitting |
A790 |
A790 |
A789 |
A789 |
A240 |
A276 |
A182 |
Mechanical Properties of Super Duplex 2507:
Ultimate Tensile Strength |
116 ksi minimum |
Yield |
(0.2 % offset) |
Elongation |
15 % |
Super Duplex Stainless Steel F55 is a highly alloyed stainless steel designed for use in aggressive environments. High strength, toughness, excellent corrosion resistance and its resistance to corrosion in a wide range of organic and inorganic acids are just a few characteristics that make this duplex stainless steel attractive to a variety of industries. Lastly, it is highly resistant to strong alkalis and resists corrosion in many non-oxidizing acids.
Super Duplex F55 Chemical Composition, %::
Cr |
Ni |
Mo |
C |
W |
Cu |
N |
Mn |
Si |
P |
S |
Fe |
24.0-26.0 |
6.0-8.0 |
3.0-4.0 |
0.03 max |
0.5-1.0 |
0.5-1.0 |
0.2-0.3 |
1.0 max |
1.0 max |
0.03 max |
0.01 max |
Balance |
Super Duplex F55 ASTM Specification:
Pipe & Tube |
Sheet/Plate |
Bar |
A790, A928, |
A240 |
A276 |
Mechanical Properties of Super Duplex F55:
Tensile Strength |
109 ksi |
Yield |
(0.2 % offset) |
Elongation (in 50 mm) |
25 % |