Duplex Stainless Steel

Duplex stainless steels are called “duplex” because they have a two-phase microstructure consisting of grains of ferritic and austenitic stainless steel. When duplex stainless steel is melted it solidifies from the liquid phase to a completely ferritic structure. As the material cools to room temperature, about half of the ferritic grains transform to austenitic grains (“islands”). The result is a microstructure of roughly 50% austenite and 50% ferrite. Duplex stainless steels are about twice as strong as regular austenitic or ferritic stainless steels.


Shah International supplies the below Duplex Alloy Grades : Duplex 2205/F51, Ferralium 255, Super Duplex 2507/F53, Super Duplex F55




Duplex S31803/2205/F51

UNS Number S31803, S32205

Duplex 2205 is a nitrogen enhanced duplex stainless steel that was developed to combat common corrosion problems encountered with the 300 series stainless steels. “Duplex” describes a family of stainless steels that are neither fully austenitic, like 304 stainless, nor purely ferritic, like 430 stainless. The structure of 2205 duplex stainless steel consists of austenite pools surrounded by a continuous ferrite phase. In the annealed condition, 2205 contains approximately 40-50% ferrite. Often referred to as the work horse grade, 2205 is the most widely used grade in the duplex family of stainless steels. The advantage of a duplex structure is that it combines the favorable qualities of a ferritic alloy (stress corrosion cracking resistance and high strength) with those of an austenitic alloy (ease of fabrication and corrosion resistance). Usage of 2205 Duplex stainless steel should be limited to temperatures below 600° F. Extended elevated temperature exposure can embrittle 2205 stainless.


Duplex 2205 Chemical Composition, %:

Cr

Ni

Mo

C

N

Mn

Si

P

S

Fe

22.0-23.0

4.50-6.50

3.00-3.50

0.03 max

0.14-0.20

2.00 max

1.00 max

0.03 max

0.02 max

Balance

Duplex 2205 ASTM Specification:

At Room Temperature, Investment Castings As Cast


Pipe Smls

Pipe Welded

Tube Smls

Tube Welded

Sheet / Plate

Bar

Fitting

A790

A790

A789

A789

A240

A276

A182


Mechanical Properties of Duplex 2205:

At Room Temperature, Investment Castings As Cast


Ultimate Tensile Strength

95 ksi minimum

Yield

(0.2 % offset)
65 ksi minimum







Ferralium 255/ S32550

UNS Number S32550

Ferralium 255 is a super duplex stainless steel supplied in the hot worked and annealed condition. It achieves higher strengths than most stainless steels and alternative corrosion resistant alloys, offering the potential to reduce section size and therefore weight and cost. As a 25% Cr alloy, with significant additions of copper, Ferralium® 255 offers excellent corrosion resistance in a wide variety of corrosive chemicals including sulphuric, nitric and phosphoric acid. In seawater and other chloride containing environments it also provides outstanding resistance to pitting and crevice corrosion, with Critical Pitting Temperature exceeding 50°C. Excellent ductility and impact strength at both ambient and sub-zero temperatures combine with a high resistance to abrasion, erosion and cavitation erosion.

Ferralium 255 Chemical Composition, %:

Cr

Ni

Mo

Cu

C

Mn

N

Si

P

S

Fe

24.5-26.5

5.5-6.5

3.1-3.8

1.5-2.0

0.025 max

0.8-1.2

0.20-0.25

0.70 max

0.025 max

0.005 max

Balance


Ferralium 255 ASTM Specification:

Pipe Smls

Pipe Welded

Tube Smls

Tube Welded

Sheet / Plate

Bar

A790

A790

A789

A789

A240

A479


Mechanical Properties of Ferralium 255:

Ultimate Tensile Strength

110 ksi or 760 Mpa minimum

Yield

(0.2 % offset)
80 ksi or 550 Mpa minimum

Elongation

15 %





Super Duplex S32750/F53

UNS Number S32750

Duplex 2507 is a super duplex stainless steel designed for applications which demand exceptional strength and corrosion resistance. Alloy 2507 has 25% chromium, 4% molybdenum, and 7% nickel. This high molybdenum, chromium and nitrogen content results in excellent resistance to chloride pitting and crevice corrosion attack and the duplex structure provides 2507 with exceptional resistance to chloride stress corrosion cracking. Usage of Duplex 2507 should be limited to applications below 600° F (316° C). Extended elevated temperature exposure can reduce both the toughness and corrosion resistance of alloy 2507. Duplex 2507 possesses excellent mechanical properties. Often a light gauge of 2507 material can be used to achieve the same design strength of a thicker nickel alloy. The resulting savings in weight can dramatically reduce the overall cost of fabrication.


Super Duplex 2507 Chemical Composition, %:

Cr

Ni

Mo

C

N

Mn

Si

Cu

P

S

Fe

24.0-26.0

6.0-8.0

3.0-5.0

0.03 max

0.24-0.32

1.20 max

0.80 max

0.50 max

0.035 max

0.02 max

Balance

Super Duplex 2507 ASTM Specification:

Pipe Smls

Pipe Welded

Tube Smls

Tube Welded

Sheet / Plate

Bar

Fitting

A790

A790

A789

A789

A240

A276

A182


Mechanical Properties of Super Duplex 2507:



Ultimate Tensile Strength

116 ksi minimum

Yield

(0.2 % offset)
80 ksi minimum

Elongation

15 %






Super Duplex F55

UNS Number S32760

Super Duplex Stainless Steel F55 is a highly alloyed stainless steel designed for use in aggressive environments. High strength, toughness, excellent corrosion resistance and its resistance to corrosion in a wide range of organic and inorganic acids are just a few characteristics that make this duplex stainless steel attractive to a variety of industries. Lastly, it is highly resistant to strong alkalis and resists corrosion in many non-oxidizing acids.


Super Duplex F55 Chemical Composition, %::

Cr

Ni

Mo

C

W

Cu

N

Mn

Si

P

S

Fe

24.0-26.0

6.0-8.0

3.0-4.0

0.03 max

0.5-1.0

0.5-1.0

0.2-0.3

1.0 max

1.0 max

0.03 max

0.01 max

Balance

Super Duplex F55 ASTM Specification:

Pipe & Tube

Sheet/Plate

Bar

A790, A928,
A789

A240

A276


Mechanical Properties of Super Duplex F55:


Tensile Strength

109 ksi

Yield

(0.2 % offset)
80 ksi

Elongation (in 50 mm)

25 %